Invention Grant
- Patent Title: Method for reactivating used hydrogenation treatment titania catalyst, and regenerated hydrogenation treatment titania catalyst
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Application No.: US14411083Application Date: 2013-05-16
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Publication No.: US10071370B2Publication Date: 2018-09-11
- Inventor: Shinichi Inoue , Yukitaka Wada , Akihiro Muto
- Applicant: CHIYODA CORPORATION
- Applicant Address: JP Yokohama-Shi
- Assignee: CHIYODA CORPORATION
- Current Assignee: CHIYODA CORPORATION
- Current Assignee Address: JP Yokohama-Shi
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP2012-160924 20120719
- International Application: PCT/JP2013/063706 WO 20130516
- International Announcement: WO2014/013784 WO 20140123
- Main IPC: B01J38/52
- IPC: B01J38/52 ; B01J38/12 ; B01J27/19 ; B01J27/28 ; C10G45/04 ; B01J38/02 ; B01J38/50 ; B01J23/882 ; B01J21/04 ; B01J21/06 ; B01J21/20 ; B01J31/38 ; B01J31/40 ; B01J38/48

Abstract:
Provided is a method of reactivating a used titania catalyst for hydrogenation treatment, capable of improving the catalytic activity of the used titania catalyst for hydrogenation treatment that is obtained by supporting a catalyst component on a titania support and exhibits reduced catalytic activity after having been used for hydrogenation treatment of a hydrocarbon oil, to a level comparable to that of a newly prepared fresh titania catalyst before use. The method of reactivating a used titania catalyst for hydrogenation treatment, the used titania catalyst for hydrogenation treatment being obtained by supporting a catalyst component on a titania support and exhibiting reduced catalytic activity after having been used for hydrogenation treatment of a hydrocarbon oil, includes: a coke removal step of removing a carbonaceous component on a surface of the used catalyst by heating the catalyst in an oxygen-containing gas atmosphere; an impregnation step of impregnating the carbonaceous component-removed catalyst obtained by the coke removal step with a saccharide-containing solution; and a drying step of drying the saccharide-impregnated catalyst obtained by the impregnation step, to obtain a catalyst in which a saccharide is supported.
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