- 专利标题: Process to produce polyolefin ionomers and ionomers produced thereby
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申请号: US15111178申请日: 2014-12-15
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公开(公告)号: US10167360B2公开(公告)日: 2019-01-01
- 发明人: Henry Martinez , Marc A. Hillmyer , Jeffrey C. Munro , Kim L. Walton , Morgan M. Hughes
- 申请人: Dow Global Technologies LLC , Regents of the University of Minnesota
- 申请人地址: US MI Midland US MN Minneapolis
- 专利权人: Dow Global Technologies LLC,Regents of the University of Minnesota
- 当前专利权人: Dow Global Technologies LLC,Regents of the University of Minnesota
- 当前专利权人地址: US MI Midland US MN Minneapolis
- 国际申请: PCT/US2014/070261 WO 20141215
- 国际公布: WO2015/108642 WO 20150723
- 主分类号: C08G61/08
- IPC分类号: C08G61/08
摘要:
A process to produce an ionomer comprising reacting alkyl-cis-cyclooctene and cis-cyclooctene in a mole ratio from 1:0 to 0:1, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer; hydrogenating the unsaturated polyolefin reactive telechelic pre-polymer to produce a hydrogenated polyolefin reactive telechelic pre-polymer; reacting the hydrogenated polyolefin reactive telechelic pre-polymer with at least one compound according to the formula aMx+b(R)y, wherein M is a metal, x is a charge of M, R is an alkyl, aryl, oxide, or fatty acid, y is a charge of R, a and b are integers of at least 1, and ax+by=0, to form an ionomer is provided. Further provided are ionomers produced thereby.