An electrochemical compression system utilizes a preheater to heat an electrochemically active working fluid to a superheated temperature delta prior compression. Heating the electrochemically active working fluid to a superheated temperature ensures there will be no condensation before the fluid reaches the condenser and therefore increases efficiency and effectiveness of the system. A preheater may be configured in a chamber upstream of the electrochemical compressor and one or more valves may control the delivery of the superheated fluid to the compressor. A preheater may be configured in an enclosure, having a valve at the inlet and outlet and retain the electrochemically active fluid at a superheated temperature. A preheater may be configured within or attached to a gas diffusion media, flow-filed or current collector and may be in direct communication with the fluid.