A method for wirelessly charging a portable terminal using a Radio Frequency (RF) is provided. A charging system detects one or more portable terminals within a predetermined area, and preferably requests information needed for charging to the one or more portable terminals via short-range communication, receives the information in response needed for charging from each of the one or more portable terminals. A portable terminal to be wirelessly charged from among the one or more portable terminals is selected, based on the received information needed for charging, and the charging system transmits a predetermined RF for charging to the selected portable terminal.