- 专利标题: Functionalized highly syndiotactic polystyrene and preparation method thereof
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申请号: US15501737申请日: 2015-08-13
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公开(公告)号: US10246536B2公开(公告)日: 2019-04-02
- 发明人: Dongmei Cui , Dongtao Liu , Zichuan Wang
- 申请人: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
- 申请人地址: CN Changchun
- 专利权人: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
- 当前专利权人: Changchun Institute of Applied Chemistry Chinese Academy of Sciences
- 当前专利权人地址: CN Changchun
- 代理机构: Cesari and McKenna, LLP
- 优先权: CN201410401107 20140814; CN201410401108 20140814
- 国际申请: PCT/CN2015/086856 WO 20150813
- 国际公布: WO2016/023503 WO 20160218
- 主分类号: C08F4/52
- IPC分类号: C08F4/52 ; C08F212/08 ; C08F212/14 ; C08F4/54 ; C08F2/02 ; C08F2/06 ; C08F4/12 ; C08L25/06 ; C08L25/16 ; C08F12/22 ; C08F12/30 ; C08F112/14
摘要:
Compared to the prior art, this invention provides a functionalized highly syndiotactic polystyrene, comprising a repeating unit having a structure represented by formula (I), or comprising a repeating unit having a structure represented by formula (I) and a repeating unit having a structure represented by formula (II). It is indicated by the experimental results that the syndiotacticity selectivity of the highly syndiotactic polymer provided by this invention is no less than 90%, and the proportion of the repeating unit having a structure represented by formula (I) in the polymer may be arbitrarily adjusted and may be up to 100%. Meanwhile, the oxygen- or sulfur-containing groups in the polymer may increase the polarity of the highly syndiotactic polystyrene so as to increase the blendability of the highly syndiotactic polystyrene with other polymers.
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