A cooling structure of an engine includes a cylinder head and a coolant temperature sensor. The cylinder head gas a first water jacket for cooling a combustion chamber and a second water jacket for cooling an exhaust manifold. The cylinder head includes a joining portion where coolants from the first water jacket and the second water jacket join together. The joining portion has a first coolant passage. A second coolant passage is disposed downstream of the joining portion. The temperature sensing portion is disposed in the second coolant passage. A coolant outlet of the second water jacket is defined in the first coolant passage, and is located at a position on the cylinder head cover attachment surface side in the first coolant passage. The temperature sensing portion is located at a position on the cylinder block attachment surface side in the second coolant passage.