An electrification apparatus for an electrostatic dust collector, including: a first electrode part having a shape of a plate having a plurality of through holes formed thereon in such a manner as to apply one of positive and negative electrodes thereto; and a second electrode part having protrusions each having a plurality of fine conductive fibers in such a manner as to protrude outwardly from the through holes of the first electrode part, whereby electrification performance is improved and harmful ozone and electromagnetic waves are reduced.