A data transfer system is provided. The system includes a plurality of electronic devices and a data transfer management device. The data transfer management device identifies a master device among the electronic devices, and the data transfer device make the master device as a root node of a topology architecture, wherein the master device is configured to provide data. The data transfer device calculates a maximum connection amount according to a first transfer time, wherein the data transfer device selects a plurality of slave devices among the electronic devices according to the maximum connection amount. The data transfer device divides the master device into a transmitting node queue, and arranges the slave devices into a receiving node queue in sequence. And, the data transfer device builds a plurality of layers of the topology architecture and sets a plurality of layer transfers corresponding to the layers.