Invention Grant
- Patent Title: Method for producing 1,3,3,3-tetrafluoropropene (HFO-1234ze) from 1-chloro-3,3,3-trifluoropopene (HCFO-1233zd)
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Application No.: US16177707Application Date: 2018-11-01
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Publication No.: US10450248B2Publication Date: 2019-10-22
- Inventor: Christian Jungong , Daniel C. Merkel , Haiyou Wang
- Applicant: Honeywell International Inc.
- Applicant Address: US NJ Morris Plains
- Assignee: Honeywell International Inc.
- Current Assignee: Honeywell International Inc.
- Current Assignee Address: US NJ Morris Plains
- Agency: Faegre Baker Daniels LLP
- Main IPC: C07C17/37
- IPC: C07C17/37 ; C07C17/20 ; C07C17/358 ; C07C21/18

Abstract:
A method for producing 1,3,3,3-tetrafluoropropene (HFO-1234ze, or 1234ze) from 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd, or 1233zd). In one embodiment, HFO-1233zd is subjected to a disproportionation reaction in the presence of a catalyst at an elevated temperature to produce HFO-1234ze as well as 3,3-dichloro-1,1-difluoropropene (HCFO-1232zc). The catalyst may be at least one of a chromium oxyfluoride catalyst, a chromium oxide catalyst, or a metal fluoride catalyst. The reaction may be conducted in the vapor phase at a temperature between 100° C. and 450° C. Advantageously, in the present method, substantially no hydrogen fluoride (HF) is used as a reactant, and substantially no HF is produced as a product.
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