Invention Grant
- Patent Title: High pressure free-radical polymerizations
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Application No.: US15574310Application Date: 2016-06-30
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Publication No.: US10457757B2Publication Date: 2019-10-29
- Inventor: Christopher R. Eddy , Jeffery S. Bradley , Otto J. Berbee , Sarat Munjal , Bryan Gutermuth
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agency: Dinsmore & Shohl LLP
- International Application: PCT/US2016/040288 WO 20160630
- International Announcement: WO2017/004320 WO 20170105
- Main IPC: C08F210/02
- IPC: C08F210/02 ; B01J3/00 ; B01J3/04

Abstract:
A process to form an ethylene-based polymer comprising, in polymerized form, ethylene and at least one acid comonomer, said process comprising polymerizing a reaction mixture comprising the ethylene and the acid comonomer, in a reactor configuration comprising at least one Secondary compressor, at least one pressurization device, and at least one reactor selected from the following: at least one autoclave reactor, at least one tubular reactor, or a combination thereof; and wherein the reaction mixture is polymerized in the presence of at least one free-radical initiator, and at a pressure of at least 1000 Bar; and wherein at least a portion of a comonomer composition comprising at least a portion of the acid comonomer used in the polymerization, is compressed, to form a compressed comonomer composition, in the pressurization device, up to a discharge pressure ranging from 1000 Bar to 4000 Bar, and at a discharge temperature (DT) from 10 C to 100 C; and wherein the compressed comonomer composition bypasses the Secondary compressor, and is fed, downstream from the Secondary compressor, into the reactor, and/or into one or more feed streams to the reactor.
Public/Granted literature
- US20180134824A1 HIGH PRESSURE FREE-RADICAL POLYMERIZATIONS Public/Granted day:2018-05-17
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