A wind turbine rotor blade may generally include a blade root, a blade tip opposite the blade root and a body shell extending between the blade root and the blade tip. The body shell may include a pressure side and a suction side extending between a leading edge and a trailing edge and may define an outer shell surface. The rotor blade may also include a leading edge cap coupled to the body shell at the leading edge. The leading edge cap may be formed from a fiber-reinforced composite including an inner surface extending directly adjacent to the body shell along a portion of the outer shell surface and an outer surface opposite the inner surface. The fiber-reinforced composite may include a plurality of fibers surrounded by a thermoplastic resin material, with the thermoplastic resin material extending throughout the fiber reinforced composite from the inner surface to the outer surface.