A system and method for monitoring, testing or configuring electrical devices includes an input amplifier having an input connected to a device load line to generate an output linearly proportional to a voltage on the load line. An output of the input amplifier is connected to a photodiode in an optical path with a phototransistor. The phototransistor generates an output proportional to light generated by the photodiode, and this output is amplified and passed to an analog-to-digital converter. The converter generates a digital voltage level corresponding to the amplified output of the phototransistor. Digital temperature information is used to further enhance linearity of a generated digital voltage level. Multiple quantum well photodiodes further improve measurement linearity.