The present disclosure provides a viewing angle switching structure, a display device and a viewing angle switching method. The viewing angle switching structure includes a plurality of viewing angle switching units corresponding to pixels on a display panel. Each viewing angle switching unit includes: an accommodation cavity; a first solution layer and a second solution layer in the accommodation cavity, a liquid interface being formed between the first and the second solution layers; and an electric field driving unit configured to generate a driving electric field to be applied to the accommodation cavity. The first solution layer has a refractive index different from the second solution layer. The first solution layer includes a transparent conductive solution and the second solution layer includes a transparent non-conductive solution. A shape of the liquid interface between the first and the second solution layers is changeable under the effect of the driving electric field.