Emissive layer structures for organic emissive devices and emissive devices containing such structures are provided. The emissive layer includes one or more sub-layers or similar regions. A fluorescent emitter and two compounds that may form an exciplex are distributed within the sub-layers so as to enhance Forster transitions from the exciplex to the fluorescent acceptor and suppress undesirable Dexter transitions from the exciplex to the fluorescent acceptor.