Methods and formulations for joining preceramic polymers in the fabrication of ceramic assemblies
Abstract:
Some variations provide a process for fabricating a ceramic structure, the process comprising: producing a plurality of preceramic polymer parts; chemically, physically, and/or thermally joining the preceramic polymer parts together, to generate a preceramic polymer structure; thermally treating the preceramic polymer structure, to generate a ceramic structure; and recovering the ceramic structure. The process may employ additive manufacturing, subtractive manufacturing, casting, or a combination thereof. A composite overwrap may be applied to the preceramic polymer structure prior to pyrolysis, and the composite overwrap also pyrolyzes to a ceramic composite and is a part of the final ceramic structure. The ceramic structure may be silicon oxycarbide, silicon carbide, silicon nitride, silicon oxynitride, silicon carbonitride, silicon boronitride, silicon boron carbonitride, or boron nitride, for example. The ceramic structure may have at least one dimension of 1 meter or greater, and may be a fully integrated ceramic object with no seams.
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