A photovoltaic power system includes a photofuel having a molecular structure to emit light, and a receptacle including the photofuel disposed within. One or more photovoltaic cells are positioned within the receptacle to receive light emitted from the photofuel, and a negative electrode is coupled to the one or more photovoltaic cells. A positive electrode is coupled to the one or more photovoltaic cells to produce an electrical potential between the negative electrode and the positive electrode when a photocurrent is generated by the one or more photovoltaic cells in response to the one or more photovoltaic cells receiving the light emitted from the photofuel.