发明授权
- 专利标题: Fluid catalytic cracking with catalyst system containing modified beta zeolite additive
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申请号: US16985588申请日: 2020-08-05
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公开(公告)号: US11142703B1公开(公告)日: 2021-10-12
- 发明人: Omer Refa Koseoglu , Robert Peter Hodgkins , Mitsunori Watabe , Koji Uchida
- 申请人: Saudi Arabian Oil Company , JGC Catalysts and Chemicals, Ltd. , Japan Cooperation Center Petroleum
- 申请人地址: SA Dhahran; JP Kawasaki; JP Tokyo
- 专利权人: Saudi Arabian Oil Company,JGC Catalysts and Chemicals, Ltd.,Japan Cooperation Center Petroleum
- 当前专利权人: Saudi Arabian Oil Company,JGC Catalysts and Chemicals, Ltd.,Japan Cooperation Center Petroleum
- 当前专利权人地址: SA Dhahran; JP Kawasaki; JP Tokyo
- 代理机构: Dinsmore & Shohl LLP
- 主分类号: C10G11/05
- IPC分类号: C10G11/05 ; C10G11/18 ; B01J29/12 ; B01J29/74 ; B01J35/10 ; B01J29/70 ; C10L1/06
摘要:
Methods for cracking a hydrocarbon oil include contacting the hydrocarbon oil with a catalyst system in a fluidized catalytic cracking unit to produce light olefins and gasoline fuel. The catalyst system includes a FCC base catalyst and a catalyst additive. The FCC base catalyst includes a Y-zeolite. The catalyst additive includes a framework-substituted *BEA-type zeolite. The framework-substituted *BEA-type zeolite has a modified *BEA framework. The modified *BEA framework is a *BEA aluminosilicate framework modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms selected from titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof. The FCC base catalyst may include a framework-substituted ultra-stable Y (USY)-zeolite as the Y-zeolite. The framework-substituted USY-zeolite has USY aluminosilicate framework modified by substituting a portion of framework aluminum atoms with titanium atoms, zirconium atoms, hafnium atoms, or combinations thereof.
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