The invention relates to an electrolysis system to conduct oxidation and reduction reactions, comprising one or more electrolytic cells, with each one of them being formed by at least a pair of electrodes and an electrolyte provided between said electrodes, wherein the assembly of said one or more electrolytic cells defines an electrolyzer; and an energy source that supplies an electrical signal to the electrolyzer; wherein said electrolytic cell is built in the form of a capacitor of cylindrical plates, wherein said cylindrical plates are defined by the electrodes of the electrolytic cell formed by tubes arranged in a substantially concentric way within each other, thus defining a central electrode, an outer electrode and a space between electrodes, wherein the central electrode corresponds to the anode of the capacitor, the outer electrode to the cathode of the capacitor and the electrolyte to the dielectric means of the capacitor; wherein the electrical signal received by the electrolytic cell or cells that form the electrolyzer correspond to a direct current pulse, wherein said pulse is configured for each electrolyzer's electrolytic cell to operate: In a charge transient regime of each cell during the current pulse; and In a discharge transient regime of each cell during the time between current pulses; wherein said charge and discharge transient regimes are defined by the construction of each electrolytic cell in the form of a cylindrical plates capacitor. In addition, the invention also relates to associated method and uses.