The invention relates to a cleaning robot and a material identification method thereof, which is suitable for cleaning robots. The cleaning robot is pre-set with a threshold comparison table and comprises a plurality of comparison thresholds, wherein each comparison threshold defines an interval of accumulated energy information accumulated by the moving plane of different materials within a predetermined period of time. The cleaning robot generates accumulated energy information during the movement, so that the cleaning robot can find the comparison threshold corresponding to the accumulated energy information from the threshold comparison table, and then determines the material of the moving plane contacted by the cleaning robot.