- 专利标题： Hydrocarbon-soluble halogen and thiolate/magnesium exchange reagents
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申请号： US16651790申请日： 2018-09-20
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公开(公告)号： US11236113B2公开(公告)日： 2022-02-01
- 发明人: Paul Knochel , Dorothée Ziegler , Meike Simon
- 申请人： ALBEMARLE GERMANY GMBH , Ludwig-Maximilians-Universität München
- 申请人地址： DE Frankfurt am Main; DE Munich
- 专利权人： ALBEMARLE GERMANY GMBH,Ludwig-Maximilians-Universität München
- 当前专利权人： ALBEMARLE GERMANY GMBH,Ludwig-Maximilians-Universität München
- 当前专利权人地址： DE Frankfurt am Main; DE Munich
- 代理机构： McGlinchey Stafford, PLLC
- 代理商 R. Andrew Patty, II
- 优先权： DE102017217230.4 20170927,DE102018200805.1 20180118
- 国际申请： PCT/EP2018/075506 WO 20180920
- 国际公布： WO2019/063418 WO 20190404
- 主分类号： C07B49/00
- IPC分类号： C07B49/00 ; C07F3/02 ; C07C41/22 ; C07C41/60 ; C07D211/16 ; C07C29/70 ; C07C41/14 ; C07F1/02
摘要：
The invention relates to hydrocarbon-soluble halogen or thiolate/magnesium exchange reagents of the general formula R1MgR11-n(OR3)n.LiOR2.(1−n)LiOR3.aDonor in which: R1 is a C1-C8 alkyl and OR2 as well as OR3 are same or different and represent primary, secondary, or tertiary alkoxide residues having 3 to 18 carbon atoms, wherein R2 and/or R3 can for their part contain an alkoxy substituent OR4; a assumes a value of 0 to 2, n assumes a value between 0 and 1, and the donor is an organic molecule containing at least 2 nitrogen atoms.
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