- 专利标题: Method for producing paraxylene using a simulated moving-bed step, and a step of fractionating two fractions in a two-section column
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申请号: US17256290申请日: 2019-06-21
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公开(公告)号: US11242302B2公开(公告)日: 2022-02-08
- 发明人: Isabelle Prevost , Jerome Pigourier , Gerard Hotier
- 申请人: AXENS
- 申请人地址: FR Rueil Malmaison
- 专利权人: AXENS
- 当前专利权人: AXENS
- 当前专利权人地址: FR Rueil Malmaison
- 代理机构: Millen White Zelano and Branigan, PC
- 代理商 John Sopp
- 优先权: FR1856049 20180629
- 国际申请: PCT/EP2019/066445 WO 20190621
- 国际公布: WO2020/002142 WO 20200102
- 主分类号: C07C7/04
- IPC分类号: C07C7/04 ; C07C7/13 ; C07C7/00 ; B01D3/14 ; B01D3/32 ; B01D15/18 ; C07C5/27
摘要:
The present invention describes a process for obtaining para-xylene from a feedstock containing xylenes, ethylbenzene and C9+ hydrocarbons, said process comprising a single stage A of separation in a simulated moving bed carried out with a zeolite as adsorbent and a desorbent and making it possible to obtain at least three fractions, a fraction A1 comprising a mixture of para-xylene and of desorbent and two fractions A21, A22 comprising ethylbenzene (EB), ortho-xylene (OX) and meta-xylene (MX) and desorbent, said stage is carried out at a temperature between 20° C. and 250° C., under a pressure between the bubble pressure of the xylenes at the operating temperature and 2.0 MPa, and with a ratio by volume of the desorbent to the feedstock in the unit for separation 2 in a simulated moving bed is between 0.4 and 2.5, a stage B of fractionation by distillation in a 2-cut distillation column of the fractions A21 and A22 resulting from stage A, in which said fractions are introduced separately at distinct injection points, and makes it possible to obtain a fraction B2 containing ethylbenzene, ortho-xylene and meta-xylene, and a fraction B42 devoid of aromatic compounds having 8 carbon atoms and containing desorbent.
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