Invention Grant
- Patent Title: Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process
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Application No.: US16469617Application Date: 2017-12-12
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Publication No.: US11279781B2Publication Date: 2022-03-22
- Inventor: Noureddine Ajellal , Anna Fait , Luigi Resconi
- Applicant: BOREALIS AG
- Applicant Address: AT Vienna
- Assignee: BOREALIS AG
- Current Assignee: BOREALIS AG
- Current Assignee Address: AT Vienna
- Agency: Meunier Carlin & Curfman LLC
- Priority: EP16204328 20161215
- International Application: PCT/EP2017/082434 WO 20171212
- International Announcement: WO2018/108918 WO 20180621
- Main IPC: C08F4/6592
- IPC: C08F4/6592 ; C08F210/16 ; C07F17/00

Abstract:
Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising: (i) a metallocene complex of formula (I) wherein M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula I has M=Hf; X is a sigma ligand; R are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C6-C10 aryl, C4-C10 heteroaryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms; R1 is a C6-C10 aryl or C6-C20 alkylaryl group optionally containing up to 2 heteroatoms or silicon atoms or a C4-C10 heteroaryl group; R2 is a C4-C20 cycloalkyl group, optionally carrying alkyl substituents in beta-positions, of formula (II) in which R′ can be the same or can be different from each other and can be hydrogen or is defined as R and n is 1 to 17; and (ii) a boron containing cocatalyst.
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