A system includes a table and a material detection system. The material detection system includes a transmit chain configured to generate first radio frequency (RF) signals and a transmit probe configured to transmit the first RF signals towards an item through open space. The material detection system also includes a receive probe configured to receive second RF signals from the item through open space, where the second RF signals have one or more characteristics indicative of one or more materials within the item. The material detection system further includes a receive chain configured to process the second RF signals and at least one processing device configured to identify the one or more materials within the item using nuclear quadrupole resonance (NQR) spectrometry based on the processed second RF signals. The transmit and receive probes are positioned in an upper portion of the table.