A light-emitting device includes: an anode; a cathode facing the anode; an emission layer between the anode and the cathode; and an electron control layer between the emission layer and the cathode, wherein the electron control layer includes an electron control compound represented by Formula 5: A method of manufacturing the light-emitting device includes: forming an emission layer on an anode; and forming an electron control layer on the emission layer, wherein the electron control layer includes an electron control compound represented by Formula 5.