A pressure sensitive adhesive sheet for batteries that includes a base material and a pressure sensitive adhesive layer provided on one surface side of the base material and containing inorganic fine particles. When D50 and D90 are defined as a volume-based accumulated 50% particle diameter of the inorganic fine particles and a volume-based accumulated 90% particle diameter of the inorganic fine particles, respectively, in a particle size distribution of the inorganic fine particles in the pressure sensitive adhesive layer, the D50 is 0.5 μm or more and 2.8 μm or less, and the ratio of the D90 to the D50 (D90/D50) is 1.3 or more and 2.0 or less. The particle size distribution is measured by image analysis on a surface of the pressure sensitive adhesive layer opposite to the base material.