A barrier coating resin formulation comprising at least one polycarbosilane preceramic polymer, at least one organically modified silicon dioxide preceramic polymer, at least one filler, and at least one solvent. A barrier coating comprising a reaction product of the at least one polycarbosilane preceramic polymer and the at least one organically modified silicon dioxide preceramic polymer and the at least one filler is also disclosed, as are articles comprising the barrier coating, rocket motors comprising the barrier coating, and methods of forming the articles.