A method of producing chemical pulp including at least the following steps: a) wood chips or other comminuted ligno-cellulosic fibrous material is treated with a polysulfide-containing cooking liquor in an impregnation stage at a temperature of 90-145° C., and b) slurry of fibrous material from step a) is heated into cooking temperature and cooked for producing pulp having a desired kappa number. After step a) mercaptide ions are added into the slurry of fibrous material and the fibrous material is treated at cooking temperature in step b).