Invention Grant
- Patent Title: Particle size control of supported chromium catalysts in loop slurry polymerization reactors
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Application No.: US17716027Application Date: 2022-04-08
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Publication No.: US11512154B2Publication Date: 2022-11-29
- Inventor: Max P. McDaniel , Carlton E. Ash , Kathy S. Clear , Eric D. Schwerdtfeger , Carlos A. Cruz , Jeremy M. Praetorius
- Applicant: Chevron Phillips Chemical Company LP
- Applicant Address: US TX The Woodlands
- Assignee: Chevron Phillips Chemical Company LP
- Current Assignee: Chevron Phillips Chemical Company LP
- Current Assignee Address: US TX The Woodlands
- Agency: Merchant & Gould P.C.
- Main IPC: C08F10/02
- IPC: C08F10/02 ; B01J8/08 ; B01J19/24 ; C08K3/08 ; C08K3/36 ; C08F4/69

Abstract:
Supported chromium catalysts containing a solid oxide and 0.1 to 15 wt. % chromium, in which the solid oxide or the supported chromium catalyst has a particle size span from 0.5 to 1.4, less than 3 wt. % has a particle size greater than 100 μm, and less than 10 wt. % has a particle size less than 10 μm, can be contacted with an olefin monomer in a loop slurry reactor to produce an olefin polymer. Representative ethylene-based polymers produced using the chromium catalysts have a HLMI of 4 to 70 g/10 min, a density from 0.93 to 0.96 g/cm3, from 150 to 680 ppm solid oxide (such as silica), from 1.5 to 6.8 ppm chromium, and a film gel count of less than 15 catalyst particle gels per ft2 of 25 micron thick film and/or a gel count of less than or equal to 50 catalyst particles of greater than 100 μm per five grams of the ethylene polymer.
Public/Granted literature
- US20220227897A1 PARTICLE SIZE CONTROL OF SUPPORTED CHROMIUM CATALYSTS IN LOOP SLURRY POLYMERIZATION REACTORS Public/Granted day:2022-07-21
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