Methods, systems, and apparatuses for producing one or more of trioxygen, hydrogen and its ions, oxygen and its ions, hydrons, hydroperoxyls, and electronically modified oxygen derivatives from oxidizing agents that are exposed to photon emissions at a wavelength in a range of 0.01 nm to 845 nm, wherein wavelengths that photo-dissociate trioxygen may be excluded. The methods, systems and apparatuses enhance the effectiveness of photo-oxidation, photocatalytic, and/or photochemical combined with photocatalytic reactions.