A power transmission chain (2) for use with a drive member (4) having a plurality of teeth (6), and wherein: (i) the power transmission chain (2) comprises a plurality of chain links (8) which are pivotally connected together by connecting members (9) and pivot arrangements (10) so that the power transmission chain (2) can pass around the drive member (4) in use; (ii) each one of the pivot arrangements (10) comprises first and second pivots (12, 14) which extend towards each other from opposite sides (16, 18) of the chain links (8); (iii) the first and second pivots (12, 14) have adjacent ends (20, 22) which face each other and which are spaced apart; (iv) the power transmission chain (2) comprises a plurality of engaging formations (24) for enabling engagement with the drive member (4); (v) the engaging formations (24) are positioned between the adjacent ends (20, 22) of the first and second pivots (12, 14); and the engaging formations (24) and the spacing apart of the adjacent ends (20, 22) of the first and second pivots (12, 14) cause the power transmission chain (2) in use always to be positioned on the drive member (4) for maximum efficiency of drive transfer between the drive member (4) and the power transmission chain (2), and irrespective of the diameter of the drive member (4).