Invention Grant
- Patent Title: Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
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Application No.: US16271451Application Date: 2019-02-08
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Publication No.: US11673849B2Publication Date: 2023-06-13
- Inventor: Tan-Jen Chen
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C07C15/08
- IPC: C07C15/08 ; B01J29/70 ; C07C15/06 ; C07C15/04 ; B01J29/03 ; C07C2/86

Abstract:
A process is described for producing paraxylene, in which an aromatic hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated aromatic product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index≤5, and the alkylation conditions comprise a temperature less than 500° C. The alkylation catalyst may be selectivated to produce a higher than equilibrium amount of paraxylene by using a molar ratio of alkylating agent to aromatic of at least 1:4.
Public/Granted literature
- US20190330129A1 Process for Selectivating Catalyst for Producing Paraxylene by Methylation of Benzene and/or Toluene Public/Granted day:2019-10-31
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