A coefficient of friction (COF) sensor on a carrier roll surface wetted with fountain solution transferred from an imaging member measures COF of the wetted carrier roll surface in real-time, even between or during printing operations. The transferred fountain solution may be concentrated and/or chilled to solidify before the measurement. The measured COF is used in a feedback loop to actively control the fountain solution layer thickness by adjusting the volumetric feed rate of fountain solution added onto the imaging member surface during an imaging or other printing operation to reach a desired uniform thickness for the printing. This fountain solution monitoring system may be fully automated.