An optically transparent protective coating is described that remains stable at elevated temperatures associated with optical fiber-based sensor applications and is sufficiently transparent to allow for conventional fiber Bragg gratings (FBGs) to be formed by directly writing through the coating. In particular, vinyl group-containing silicone polymers have been found to provide the UV transparency required for a write-through coating (WTC) and promising mechanical properties for protecting the optical fibers, while also being able to withstand elevated temperatures for extended periods of time.