发明授权
- 专利标题: Catalyst mixture
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申请号: US17276437申请日: 2019-09-17
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公开(公告)号: US11767376B2公开(公告)日: 2023-09-26
- 发明人: Raffaele Bernardo , Gerardus Van Doremaele , Wouter Van Meerendonk , Peter Windmuller
- 申请人: ARLANXEO NETHERLANDS B.V.
- 申请人地址: NL Geleen
- 专利权人: ARLANXEO NETHERLANDS B.V.
- 当前专利权人: ARLANXEO NETHERLANDS B.V.
- 当前专利权人地址: NL Geleen
- 代理机构: Norris McLaughlin PA
- 优先权: EP 195257 2018.09.18
- 国际申请: PCT/EP2019/074869 2019.09.17
- 国际公布: WO2020/058267A 2020.03.26
- 进入国家日期: 2021-03-15
- 主分类号: C08F4/6592
- IPC分类号: C08F4/6592 ; C08F236/20 ; C08L23/08 ; C08F4/659 ; C08F210/18
摘要:
The present invention relates to a catalyst mixture containing at least one metal complex according to the formula (1)
CyLMZp (1),
and at least one metal complex according to the formula (2)
InLMZp (2),
wherein
Cy is a substituted cyclopentadienyl ligand that contains the substituents R1, R2 and 3 additional methyl groups, wherein
R1 means H, halogen or a C3-C20 substituent and
R2 means a C1-C20 substituent,
In is an indenyl ligand, optionally substituted with one or more substituents R3, wherein the one or more substituents R3 mean independently C1-C20 hydrocarbyl substituents,
and independently for each formula (1) and (2)
M is a group 4 metal
Z independently is an anionic ligand,
p is number of 1 to 2, preferably 2, and
L is an amidinate ligand of the formula (3)
wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom.
CyLMZp (1),
and at least one metal complex according to the formula (2)
InLMZp (2),
wherein
Cy is a substituted cyclopentadienyl ligand that contains the substituents R1, R2 and 3 additional methyl groups, wherein
R1 means H, halogen or a C3-C20 substituent and
R2 means a C1-C20 substituent,
In is an indenyl ligand, optionally substituted with one or more substituents R3, wherein the one or more substituents R3 mean independently C1-C20 hydrocarbyl substituents,
and independently for each formula (1) and (2)
M is a group 4 metal
Z independently is an anionic ligand,
p is number of 1 to 2, preferably 2, and
L is an amidinate ligand of the formula (3)
wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom.
公开/授权文献
- US20220056162A1 CATALYST MIXTURE 公开/授权日:2022-02-24
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