- 专利标题: Macromonomeric stabilizer, preparation method thereof, and method for preparing polymeric polyol
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申请号: US17295581申请日: 2018-12-26
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公开(公告)号: US11795265B2公开(公告)日: 2023-10-24
- 发明人: Fuguo Li , Changxun Ju , Yang Liu , Chengqun Qin , Bin Liu , Xunkun Wu , Jing Li , Ye Sun , Bing Zheng , Lunpeng Wang
- 申请人: WANHUA CHEMICAL GROUP CO., LTD.
- 申请人地址: CN Shandong
- 专利权人: WANHUA CHEMICAL GROUP CO., LTD.
- 当前专利权人: WANHUA CHEMICAL GROUP CO., LTD.
- 当前专利权人地址: CN Shandong
- 代理机构: Norton Rose Fulbright US LLP
- 代理商 James R. Crawford
- 国际申请: PCT/CN2018/123892 2018.12.26
- 国际公布: WO2020/132940A 2020.07.02
- 进入国家日期: 2021-05-20
- 主分类号: C08F290/06
- IPC分类号: C08F290/06 ; C08G18/48 ; C08G18/63 ; C08G65/26 ; C08J9/00
摘要:
A macromonomeric stabilizer, a preparation method thereof, a method for preparing a polymeric polyol using same, and the polymeric polyol prepared. Also disclosed are a soft polyurethane foam obtained by foaming a composition of the polymeric polyol prepared and a polyisocyanate, and a molded product comprising the soft polyurethane foam. The preparation method of the macromonomeric stabilizer comprises the following steps: reacting a polyol with a tricarboxylate not comprising a polymerizable ethylenically unsaturated double bond, or a derivative thereof, to form an adduct; and reacting the resulting adduct with an epoxide comprising a polymerizable ethylenically unsaturated double bond. The macromonomeric stabilizer of the present invention has a low viscosity, comprises a plurality of active sites, and can be directly used in subsequent reactions. The preparation method of the macromonomeric stabilizer can be carried out under normal pressure, without the need for end-blocking with ethylene oxide.
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