Method for production of elemental sulfur by part or fully catalytic oxidation of Claus tail gas
Abstract:
A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.
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