- 专利标题: Process for making propene oxide
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申请号: US18046150申请日: 2022-10-12
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公开(公告)号: US11873285B2公开(公告)日: 2024-01-16
- 发明人: Maik Bernhard , Juliette Halli , Marc Brendel , Sören Götz , Hans-Christian Dietz
- 申请人: Evonik Operations GmbH , thyssenkrupp Uhde GmbH
- 申请人地址: DE Essen
- 专利权人: Evonik Operations GmbH,thyssenkrupp Uhde GmbH
- 当前专利权人: Evonik Operations GmbH,thyssenkrupp Uhde GmbH
- 当前专利权人地址: DE Essen; DE Dortmund
- 代理机构: Grüneberg and Myers PLLC
- 优先权: EP 202651 2021.10.14
- 主分类号: C07D301/12
- IPC分类号: C07D301/12 ; C07D301/32 ; C07D303/04
摘要:
A process for making propene oxide involves reacting propene with hydrogen peroxide in the presence of methanol, a titanium zeolite epoxidation catalyst, and nitrogen containing compounds present in an amount of from 100 to 3000 mg/kg of hydrogen peroxide. Non-reacted propene is separated from the reaction mixture; the propene depleted reaction mixture is continuously distilled in a distillation column providing an overhead product stream containing propene oxide and methanol and a bottoms product stream; and propene oxide is separated from the overhead product stream. An acid is added to the propane depleted reaction mixture and/or to the distillation column at the same level or above the feed point for the propene depleted reaction mixture and/or contacted to the feed to the distillation column to provide an apparent pH in the bottoms product stream of from 3 to 4.5, which reduces the nitrogen content of the separated propene oxide.
公开/授权文献
- US20230120363A1 Process for making propene oxide 公开/授权日:2023-04-20
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