An optical fiber includes: a core portion made of glass; and a cladding portion made of glass, having a refractive index lower than the refractive index of the core portion, and positioned on an outer periphery of the core portion. Further, the cladding portion has an outer diameter smaller than 100 μm, and the core portion has a relative refractive-index difference of 0.32% to 0.40% with respect to the cladding portion.