A system may include one or more downhole tools, where a first downhole tool includes a pulsed neutron generator to emit neutrons into a borehole of a geological formation and one or more gamma-ray detectors to obtain a measurement of gamma-ray emissions, of a borehole environment, induced by the emitted neutrons. The system may also include data processing circuitry to determine a Sigma value associated with the borehole environment based on the measurement and determine elemental concentrations, excluding lithium, based on one or more gamma-ray energy spectra obtained via the one or more downhole tools. The data processing circuitry may also determine an elemental Sigma contribution of the elements other than lithium based on the elemental concentrations, determine a lithium Sigma contribution based on a difference between the Sigma value and the elemental Sigma contribution, and determine a lithium concentration within the borehole environment based on the lithium Sigma contribution.