Invention Application
US20020037979A1 MIXED ZIEGLER/METALLOCENE CATALYSTS FOR THE PRODUCTION OF BIMODAL POLYOLEFINS
审中-公开
用于生产双峰聚合物的混合ZIEGLER / METALLOCENE催化剂
- Patent Title: MIXED ZIEGLER/METALLOCENE CATALYSTS FOR THE PRODUCTION OF BIMODAL POLYOLEFINS
- Patent Title (中): 用于生产双峰聚合物的混合ZIEGLER / METALLOCENE催化剂
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Application No.: US09473491Application Date: 1999-12-28
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Publication No.: US20020037979A1Publication Date: 2002-03-28
- Inventor: ROBERT CHARLES JOB , JESSICA ANN COOK , SUN-CHUEH KAO
- Main IPC: C08F004/44
- IPC: C08F004/44

Abstract:
A self-supported hybrid olefin polymerization catalyst comprising a Ziegler-Natta component and a metallocene component whereby the metallocene component is affixed to the Ziegler-Natta component is disclosed. In the hybrid catalyst, the Ziegler-Natta component includes a solid complex of magnesium, transition metal, and alkoxide moieties where the transition metal is selected from one or more metals having an oxidation state of null3, null4, null5, and mixtures thereof. A method of making the hybrid catalyst and a method of polymerizing olefins using the hybrid catalyst also are disclosed. The hybrid catalyst is capable of producing polyolefins having a broad molecular weight, or bimodal distribution in high yield.
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