A structure for generating ozone using a high voltage durable silicone rubber electric conductor as a medium, the structure is advantageous in having long life of use, low cost of production and good working efficiency. The ozone generating structure is comprised of an electric circuit board, a high voltage durable silicone rubber electric conductor and a conducting tube. The conducting tube is formed by winding a stainless steel wire which is hardly to be oxidated; and has a central passage, both ends thereof are fixed on the circuit board to connect with a first connecting line. The electric conductor has a free end extended through the central passage of the conducting tube, and has an electric conducting end welded to the circuit board to connected with a seconded connecting line. When the first and seconded connecting lines are given with a high voltage below the regulated value for the electric conductor, the surface insulation layer of the electric conductor acts as a medium between an inner wire thereof and the conducting tube and forms superficially a space having electric halation. The air in the space having the electric halation discharges under a high voltage, and ozone is generated.