An image-receiving layer composition is coated on a surface of a substrate of an ink-jet recording medium, used to form an image with the ink-jet system, to form an image-receiving layer. The composition includes an epoxy compound, an oxetane compound and a photo-cationic polymerization initiator. The composition is cured with an active energy beam. An image of an ink is formed on the image-receiving layer. Further, an overcoat layer is formed on the image. Also the ink and the overcoat layer may include an epoxy compound, an oxetane compound and a photo-cationic polymerization initiator.