Invention Application
- Patent Title: Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
- Patent Title (中): 减少烯烃聚合反应的载体催化剂,制备方法及其应用
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Application No.: US10272789Application Date: 2002-10-17
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Publication No.: US20040077807A1Publication Date: 2004-04-22
- Inventor: Karen L. Neal-Hawkins , Sandor M. Nagy , William J. Sartain , Kiran M. Gupte , Kenneth W. Johnson
- Applicant: Equistar Chemicals L.P.
- Applicant Address: TX Houston
- Assignee: Equistar Chemicals L.P.
- Current Assignee: Equistar Chemicals L.P.
- Current Assignee Address: TX Houston
- Main IPC: C08F004/44
- IPC: C08F004/44 ; B01J031/00

Abstract:
Olefin polymerization in the presence of heterogeneous supported catalysts is improved by incorporating into the supported catalyst a unifunctional hydrophobic tether comprising a hydrophobic portion containing no basic nitrogen and a univalent reactive group. The unifunctional hydrophobic tether reduces fouling and sheeting in gas phase polymerization processes and improves polymer morphology and bulk density in slurry polymerization processes, while substantially maintaining or enhancing catalyst polymerization activity.
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