Disclosed are products that may not only kill harmful microorganisms, but may also protect the skin from harmful and irritating substances. The invention provides for formulations of antimicrobial hand soap; antibacterial topical skin barrier lotion for use on skin, over or under gloves, that moisturizes and seals out undesirable contaminants and irritants; antibacterial surface cleaner; and a validation and monitoring kit. Also included is a method for determining if employees are protected and following the protocol of application of the formulations. The products are used in combination as a system for managing microbial pathogens and irritants. The invention further provides for numerous other formulations, including, anti-itch lotion, sunscreen, spermicides, lip balm, anti-oxidant lotion, anti-aging/anti-wrinkling lotions and an insect repellent.