- 专利标题: Polyamide supported metallocene catalysts
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申请号: US11094681申请日: 2005-03-29
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公开(公告)号: US20050171307A1公开(公告)日: 2005-08-04
- 发明人: David Rauscher , William Gauthier , Shady Henry , Kai Hortmann
- 申请人: David Rauscher , William Gauthier , Shady Henry , Kai Hortmann
- 主分类号: C08F4/659
- IPC分类号: C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F110/06 ; C08F4/44
摘要:
Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene or two or more co-supported metallocenes.
公开/授权文献
- US07309678B2 Polyamide supported metallocene catalysts 公开/授权日:2007-12-18
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