发明申请
- 专利标题: Method for the production of 1,4- butanediol
- 专利标题(中): 1,4-丁二醇生产方法
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申请号: US10517263申请日: 2003-06-10
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公开(公告)号: US20050182281A1公开(公告)日: 2005-08-18
- 发明人: Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
- 申请人: Michael Hesse , Stephan Schlitter , Holger Borchert , Markus Schubert , Markus Rosch , Nils Bottke , Rolf-Hartmuth Fischer , Alexander Weck , Gunther Windecker , Gunnar Heydrich
- 优先权: DE10225926.7 20020611
- 国际申请: PCT/EP03/06062 WO 20030610
- 主分类号: C07B61/00
- IPC分类号: C07B61/00 ; C07C29/149 ; C07C31/20 ; C07C31/18
摘要:
The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C4-dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C4-dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 10 to 100 bar into a first reactor or into a first reaction zone of a reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted y-butyrolactone; b) introducing the product stream obtained in this way into a second reactor or into a second reaction zone of a reactor at a temperature of from 140° C to 260° C. and catalytically hydrogenating it in the gas phase to optionally alkyl-substituted 1,4-butanediol; steps a) and b) being carried out at the same pressure; c) removing the desired product from intermediates, by-products and any unconverted reactants; d) optionally recycling unconverted intermediates into one or both hydrogenation stages, said hydrogenation stages each using a catalyst which comprises ≦95% by weight, preferably from 5 to 95% by weight, in particular from 10 to 80% by weight, of CuO, and ≧5% by weight, preferably from 5 to 95% by weight, in particular from 20 to 90% by weight, of an oxidic support, and the product mixture removed from the first hydrogenation stage being introduced without further purification into the second hydrogenation stage.
公开/授权文献
- US07154011B2 Method for the production of 1,4- butanediol 公开/授权日:2006-12-26
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