- 专利标题: Process for continuous production of branched polyarylene sulfides
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申请号: US10513467申请日: 2003-04-21
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公开(公告)号: US20060025632A1公开(公告)日: 2006-02-02
- 发明人: Mikiya Hayashi , Kouichi Suga
- 申请人: Mikiya Hayashi , Kouichi Suga
- 优先权: JP2002-132824 20020508
- 国际申请: PCT/JP03/05043 WO 20030421
- 主分类号: C07C319/14
- IPC分类号: C07C319/14
摘要:
A process for continuous production of a branched polyarylene sulfide, which includes pre-polymerizing a sulfur source with a dihalogenated aromatic compound in such a manner that the reaction rate of the dihalogenated aromatic compound is less than 95% so as to produce a polyarylene sulfide, prepolymer, and polymerizing the prepolymer in the presence of a branching agent while dispersing the phase of the polymer into the form of spherical droplets in the phase of a solvent. When the prepolymer is added to the solvent phase to which a phase separator is beforehand added, spherical droplets of the polymer phase can be produced.
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