发明申请
US20060052630A1 Process for the producing alkylarylsulfonates by using modified, dimerized olefins
审中-公开
通过使用改性的二聚烯烃制备烷基芳基磺酸盐的方法
- 专利标题: Process for the producing alkylarylsulfonates by using modified, dimerized olefins
- 专利标题(中): 通过使用改性的二聚烯烃制备烷基芳基磺酸盐的方法
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申请号: US10538473申请日: 2003-12-22
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公开(公告)号: US20060052630A1公开(公告)日: 2006-03-09
- 发明人: Thomas Narbeshuber , Ulrich Steinbrenner , Dag Wiebelhaus , Nils Bottke
- 申请人: Thomas Narbeshuber , Ulrich Steinbrenner , Dag Wiebelhaus , Nils Bottke
- 申请人地址: DE LUDWIGSHAFEN
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: DE LUDWIGSHAFEN
- 优先权: DE10261481.4 20021223
- 国际申请: PCT/EP03/14712 WO 20031222
- 主分类号: C07C303/06
- IPC分类号: C07C303/06
摘要:
The invention relates to processes for the preparation of alkylarylsulfonates by a) reaction of a C4-olefin mixture over a metathesis catalyst to prepare an olefin mixture comprising 2-pentene and/or 3-hexene and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) in the presence of a dimerization catalyst to give a mixture comprising C10-12-olefins and optional removal of the C10-12-olefins, c) reaction of the C10-12-olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkyl aromatic compounds obtained in stage c) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.
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