发明申请
- 专利标题: Method for producing chlorine from hydrochloric from hydrochloric aid
- 专利标题(中): 从盐酸辅助的盐酸生产氯的方法
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申请号: US10532725申请日: 2003-10-27
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公开(公告)号: US20060099138A1公开(公告)日: 2006-05-11
- 发明人: Christian Walsdorff , Martin Fiene , Christian Kuhrs , Eckhard Stroefer , Klaus Harth
- 申请人: Christian Walsdorff , Martin Fiene , Christian Kuhrs , Eckhard Stroefer , Klaus Harth
- 申请人地址: DE Ludwigshafen 67056
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen 67056
- 优先权: DE10250131.9 20021028
- 国际申请: PCT/EP03/11910 WO 20031027
- 主分类号: C01B7/00
- IPC分类号: C01B7/00
摘要:
Process for preparing chlorine from hydrochloric acid, which comprises the steps: a) providing a hydrochloric acid feed stream I; b) providing a hydrochloric acid recycle stream II; c) separating off a hydrogen chloride stream IV from the hydrochloric acid feed stream I and the hydrochloric acid recycle stream II in a distillation step; d) feeding the hydrogen chloride stream IV, an oxygen-containing steam V and, if desired, an oxygen-containing recycle stream Va into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst to give a product gas stream VI comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor; e) separating off hydrogen chloride and water from the product gas stream VI in an absorption step to give a gas stream VII and the hydrochloric acid recycle stream II; f) if desired, drying the gas stream VII; g) separating off an oxygen-containing stream from the gas stream VII and, if desired, recirculating at least part of this as oxygen-containing recycle stream Va to the oxidation zone, leaving a chlorine-containing product stream VIII; h) if desired, further purifying the chlorine-containing product stream VIII.
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