发明申请
US20060106270A1 Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst 有权
使用移动床技术和水热稳定的双功能催化剂选择性地将含氧化合物转化为丙烯

  • 专利标题: Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst
  • 专利标题(中): 使用移动床技术和水热稳定的双功能催化剂选择性地将含氧化合物转化为丙烯
  • 申请号: US10988136
    申请日: 2004-11-12
  • 公开(公告)号: US20060106270A1
    公开(公告)日: 2006-05-18
  • 发明人: Bryan GloverJohn ChenPeter PujadoBipin Vora
  • 申请人: Bryan GloverJohn ChenPeter PujadoBipin Vora
  • 主分类号: C07C1/00
  • IPC分类号: C07C1/00
Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst
摘要:
The average propylene cycle selectivity of an oxygenate to propylene (OTP) process using a dual-function oxygenate conversion catalyst is substantially enhanced by the use of a combination of: 1) moving bed reactor technology in the hydrocarbon synthesis portion of the OTP flow scheme in lieu of the fixed bed technology of the prior art; 2) a hydrothermally stabilized and dual-functional catalyst system comprising a molecular sieve having dual-function capability dispersed in a phosphorus-modified alumina matrix containing labile phosphorus and/or aluminum anions; and 3) a catalyst on-stream cycle time of 400 hours or less. These provisions stabilize the catalyst against hydrothermal deactivation and hold the build-up of coke deposits on the catalyst to a level which does not substantially degrade dual-function catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling maintenance of average propylene cycle yield near or at essentially start-of-cycle levels.
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